1,10-Phenanthroline–dithiooxamide (2/1)
نویسندگان
چکیده
The asymmetric unit of the title compound, C(12)H(8)N(2)·0.5C(2)H(4)N(2)S(2), contains one 1,10-phenanthroline mol-ecule and a half-mol-ecule of dithio-oxamide, which lies across a crystallographic inversion center. The 1,10-phenanthroline unit is not strictly planar, with dihedral angles between the central benzene ring and the pyridine rings of 1.42 (10) and 1.40 (10)°. In the crystal structure, two 1,10-phenanthroline mol-ecules are linked together by one dithio-oxamide via inter-molecular N-H⋯N hydrogen bonds.
منابع مشابه
Dibromidobis(1,10-phenanthroline-κ2 N,N′)cadmium(II)
The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydro-thermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(-) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The crystal packing is stabilized by inter-molecular π-π inter-actions with centroid-centroid distan...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010